Intergranular stress corrosion cracking of welded steel twi. The nickel content in austenitic stainless steels helps to reduce the rate of corrosion, particularly in acid environments. This paper discusses various cases of scc and stress induced cracking sic that normally occur with austenitic stainless steel in fertilizer plants and describes three case studies. The effect of cold work on the stresscorrosion cracking. It is found that the stress vs timetofailure curves for both alloys are divided into three regions that. Stress corrosion cracking of austenitic stainless steels 689 ld. Stress corrosion cracking of austenitic stainless steel technical bulletin ind tb009 02212020 replaces 011918 two other common specifications are mili24244 and nrc 1. Influence of carbide precipitation and rolling direction on intergranular stress corrosion cracking of austenitic stainless steels in hydrogenated hightemperature water k. In this paper, experimental results on stress corrosion cracking in austenitic stainless steels are described. Austenitic stainless steels chloride induced stress corrosion cracking cscc chumpes petroleum 16 mar 18 10.
In 2007, badak lng experienced this problem on its amine regenerator pressure vessel where the shell are insulated and made of austenitic stainless steel. Effects of surface preparation on pitting resistance. Scc tendency is slight in low ni ferritic and martensitic grades but is severe in the 810% ni austenitic steels. Stress corrosion cracking of austenitic stainless steel. The effect of cold work on stress corrosion cracking of type 302 austenitic stainless steel wire exposed to boiling 154 c, 309 f 42 weightpercent aqueous magnesium chloride solution was determined. Astm g123 002015 standard test method for evaluating. Cracking of stainless steel nozzle sleeve metallurgical. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. The boiling magnesium chloride test cracks materials with the nickel levels found in relatively resistant austenitic and duplex stainless steels, thus. Crystal orientation analysis on stress corrosion cracking.
This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride. Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. Susceptible alloys include 304l, 316l, 321, and 347. Their morphology and crystal orientation were analyzed. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. When austenitic stainless steels with sufficient carbon. The effect of salt loading on chlorideinduced stress. Issf martensitic stainless steels 10 oil and gas recovery. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. This alloy exhibits superior resistance to stresscorrosion cracking in boiling 2040% sulfuric acid. In both steels the coldworked material cw showed higher crack propagation rate than annealed one st, where the variation of the propagated crystal planes of. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical. Duplex stainless steels, austenitic stainless steels with a high nickel content 25 %. Stress corrosion cracking of austenitic stainless steel core.
Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Stress corrosion cracking of an austenitic stainless steel in. This diagram figure 1 is analogous to a similar diagram for caustic. In this study the influence of operating conditions such as chloride concentration, temperature on stress corrosion cracking of austenitic stainless steel will be investigated.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Ahmed and others published stress corrosion cracking of austenitic stainless steels in chloride environment find. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Quasicleavage facets have been detected in the stress corrosion cracking fracture of type 304 and type 316 austenitic stainless steels under an environment containing chloride. For this reason, they cant be used to serve a number of different functions. Effects of marine environments on stress corrosion cracking. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. Some 95% of 316l chemical plant equipment failures may be attributed to chloride scc. Stress corrosion cracking of an austenitic stainless steel.
Exposure of the austenitic stainless steel piping or equipment to moisture and air can lead to a potential for this type of cracking if the ss is sensitized. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Rr902 chloride stress corrosion cracking in austenitic. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. Irradiationinduced stress corrosion cracking of austenitic. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking scc of austenitic stainless and. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Effect of surface contamination of austenitic stainless steel on its susceptibility to stress corrosion at elevated. Stress corrosion cracking in duplex stainless steel. A general definition of the phenomenon is that scc is the fracture of a material by the simultaneous action of a tensile stress and a corrosive environment. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. External stress corrosion cracking escc of austenitic.
Mili24244 is a us dept of defense specification for insulation that is going to be used on the stainless steel pipe and equipment associated with nuclear propulsion. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission regulatory guide 1. On the stress corrosion cracking mechanisms of austenitic. A phenomenon that regularly plagues the standard austenitic stainless steels of type aisi 304316 is stress corrosion cracking scc. Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment vessels for the storage of plutoniumbearing materials. Carbon steel and ferritic stainless steels, with little to no nickel, do not experience cl scc, nor do high nickel alloys those with ni over 30% are much less prone. Grades with high resistance to chlorideinduced stress corrosion cracking scc duplex stainless steels, austenitic stainless steels with a high nickel content 25%. Stress corrosion cracking of aisi 304 and aisi 316 austenitic. Austenitic stainless steels are however vulnerable to stress corrosion cracking scc in specific environmental conditions including when exposed to hydrogen.
This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Stress corrosion cracking scc of duplex stainless steel. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Chloride stress corrosion cracking inspectioneering. The following sandvik grades have very good or excellent resistance to chlorideinduced stress corrosion cracking. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. In austenitic stainless steel, for example, warm chloride solutions in the presence of residual tensile stress can lead to cracking. Austenitic stainless steels are nonhardenable by heat treating. Pitting and stress corrosion cracking behavior of austenitic stainless steel weldments containing retained ferrite. Stress corrosion cracking in duplex stainless steel great.
Duplex stainless steels, austenitic stainless steels with a high nickel content 25%. The effect of cold work on the stresscorrosion cracking of. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and carbonatebicarbonate solutions. Austenitic grades, however, are susceptible to chloride stress corrosion cracking scc and are not recommended for service that combines tensile stress and the presence of chlorides, even at moderate temperatures. In aqueous chloride environments austenitic stainless steels and many nickel based alloys are common to perform poorly. For austenitic stainless steels chlorides are the major cause of stress corrosion cracking scc. They can be subject to polythionic acid stress corrosion cracking during shut down. Effects of marine environments on stress corrosion. Stress corrosion cracking of stainless steel heatexchanger of shell and tube type by cooling water. Stress corrosion cracking the international institute of.
Pdf stress corrosion cracking of austenitic stainless. Stress corrosion cracking scc of austenitic stainless. This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Crack growth data in sodium chloride solution for aisi 304 steel obtained for different metallurgical conditions, acoustic emission data recorded during crack growth and fractographic observations have been discussed with a view to identifying the operating mechanism. A model has been developed which simulates the deformation of single crystal austenitic stainless steels and captures the effects of hydrogen on stress corrosion cracking.
The major emphasis is placed on the cracking which occurs in chloride environments, although other environments are mentioned. Effects of marine environments on stress corrosion cracking of austenitic stainless steels 1011820 effective december 6, 2006, this report has been made publicly available in accordance with section 734. The general pattern of the observed failures indicates that as nuclear plants age and fluence. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in.
Lippold j and alexandrov b, phase transformations during welding and postweld heat treatment of a 12cr6. Austenitic stainless steels are widely used in hydroprocessing units. The stress corrosion cracking scc of aisi 304 and aisi 316 austenitic stainless steels in 0. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Woollin p, postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels, proc conf stainless steel world 2005, kci publishing, paper no. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Ferritic steels are also resistant to cracking but may corrode. However, ferritic steel is still fairly vulnerable to stress corrosion cracking.
The interaction of corrosion fatigue and stresscorrosion. This limits the usefulness of austenitic stainless steel for containing. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Influence of sensitization on crack growth rate of aisi 304 stainless steel as a. Stress corrosion cracking on an insulated austenitic.
Austenitic stainless steels chloride induced stress. Effects of stress and temperature on stress corrosion. Surface finishing treatments such as shot blasting and wire brushing can be beneficial in improving the integrity of machined surfaces of austenitic stainless steels. Caustic stress corrosion cracking inspectioneering. Stress corrosion cracking of austenitic stainless steels. The optical photomicrograph in figure 14 reveals the etched microstructure, a normal annealed austenitic stainless steel microstructure. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. When steel is embrittled and fails by cracking due to exposure to hydrogen in the presence of stress, the failure. In this study, ground steel surfaces were subjected to a series of sand blasting and wire brushing. Pdf stress corrosion cracking of austenitic stainless steels in. Chloride stress corrosion cracking of an austenitic. An example is hot potable water under heat transfer conditions which permit chlorides to concentrate locally. New grades most of them proprietary more resistant to stress corrosion cracking scc and sulfide stress cracking ssc are now under development and are.
These operations optimize inservice properties such as resistance to pitting corrosion and stress corrosion cracking scc. Stress corrosion cracking facts and how to reduce the risk. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Modelling hydrogen induced stress corrosion cracking in. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Contrary to previous beliefs, heataffected zones of the cracked type 304l as well as 304 ss core shroud welds and mockup shieldedmetalarc welds were free of grainboundary carbides, which shows that core shroud failure cannot be explained by classical intergranular stress corrosion cracking. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Stress corrosion cracking scc is one failure mode that may occurred on hot insulated austenitic stainless steel pressure vessels and piping. Stress corrosion cracking of austenitic stainless steels 687 in view of the ambiguity in the various mechanisms for explaining scc in austenitic stainless steels, an attempt has been made to understand further the mechanism by combining fracture mechanics, acoustic emission, metallurgical and. In general, this test method is more useful for stainless steels than the boiling magnesium chloride test of practice g36.
Austenitic stainless steels are classified in the 200 and 300 series, with 16% to 30% chromium and 2% to 20% nickel for enhanced surface quality, formability, increased corrosion and wear resistance. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Astm g123002015, standard test method for evaluating stress corrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution, astm international, west conshohocken, pa, 2015. The resistance of austenitic stainless steels to scc is related to the nickel content of the steel. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. In essence, on their own, ferritic stainless steel and austenitic stainless steel dont handle stress corrosion cracking admirably. In 2007, badak lng experienced this problem on its amine regenerator pressure vessel where the shell are insulated and made of austenitic stainless steel grade 304l. Feb 28, 2018 however, ferritic steel is still fairly vulnerable to stress corrosion cracking. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. Chloride stress corrosion cracking in austenitic stainless steel.
Stress corrosion cracking scc of uns s31603 austenitic stainless steel ass, uns s32205 duplex stainless steel dss and uns s32750. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Austenitic stainless steels suffer from scc in chlorides, caustic, and polythionic acid. Stress corrosion cracking scc is a common issue with many specialty alloys. Behaviour of stress corrosion cracking of austenitic stainless.
The intergranular penetrations are attributed to general corrosive attack rather than stress corrosion cracking scc. Sp01702018 protection of austenitic stainless steels. Why are austenitic stainless steels more susceptible to. The most susceptible austenitic grades have nickel contents in the. Stress corrosion cracking scc of austenitic stainless steel weld metal. Arioka 1 inss institute of nuclear safety system, 64 sata, mihamacho, fukui 9191205, japan. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Alloy 20 carpenter 20 is an austenitic stainless steel possessing excellent resistance to hot sulfuric acid and many other aggressive environments which would readily attack type 316 stainless. T1 effects of stress and temperature on stress corrosion cracking of austenitic stainless steels in concentrated magnesium chloride solutions.
Investigation of stress corrosion cracking of austenitic, duplex and. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. Stress corrosion cracking international institute of. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature.